Okay! Went for another drive today after 5 days of tinkering, it was GREAT and I will explain the absolute goose chase I went down.
First - Brake issues got me to remove the master and the small peg at the end of the booster, I found that when I install the master I have to push the piston for it to sit flush with the booster, I found out that it is not ideal and was probably causing my master to always have pressure when is not desired. I ground the peg so it was not engaging the master when I installed it( I will probably need a new booster but for now this will suffice my itch to drive this thing!). while I was at it popped every single piston at the caliper out and silicone greased every single one. I got fresh pads because the other ones were toast (literal toast very burnt). I lubricated every point that the brake pedal is associated with and today no sticking! I did find two further issues, my thermostat does not seem to be opening up, not sure if this is an issue with the thermostat but a new one will probably be ordered just in case. I don't think the car was overheating, my guess is it would be more apparent, I have brand new hoses and a new radiator to boot. The second new issue is that I need to pull the brake pedal up after depressing it, I did replace the return spring with a rather weak one so I probably need to get a better one. The stronger return spring "returned" onto my face causing a rather nice bruise, thank god I have 2 months until my wedding!
Second - I was running the incorrect coil, car came with both a Bosch "black" and a "blue" and it took me chasing the ignition wire to see if the previous owner removed the resistor, and they did. So a new 3ohm flamethrower and she is running very very smoothly vs the "blue"!!! I definitely need to rebuild the ratty 32/36 that is on there now which will further help.
All in all, I was able to start from a stop in second gear, I have no hesitation from the engine and I was left with a big old dumb smile on my face!
On to the next thing, thank you, EVERYONE! @popovm, @dlefebvre02, @John76(my savior), @Mike Self, @Mark92131, @2002iii @Dudelandand @Son of Marty for getting another 02 back on the road!